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Skeletal remains of two equid species, Equus caballus (horse) and Equus asinus (donkey), have been found in archaeological contexts throughout Iberia since the Palaeolithic and Chalcolithic periods, respectively. These two species play different economic and cultural roles, and therefore it is important to be able to distinguish between the two species to better understand their relative importance in the past human societies. The most reliable morphological features for distinguishing between the two domesticated equids are based on cranial measure-ments and tooth enamel folds, leading to only a small percentage of archaeological remains that can be identified to species. Ancient DNA (aDNA) analysis can be used to reliably distinguish the two equids, but it can be cost prohibitive to apply to large assemblages, and aDNA preservation of non-cranial elements is often low. Collagen peptide mass fingerprinting by matrix-assisted laser desorption time-of-flight (MALDI-TOF) mass spectrometry, also known as zooarchaeology by mass spectrometry (ZooMS), is a minimally destructive and cost-effective alternative to aDNA analysis for taxonomic determination. However, current ZooMS markers lack resolution below the genus level Equus. In this paper, we report a novel ZooMS peptide marker that reliably distinguishes between horses and donkeys using the enzyme chymotrypsin. We apply this peptide marker to taxonomically identify bones from the Iberian Peninsula ranging from the Iron Age to the Late Modern Period. The peptide biomarker has the potential to facilitate the collection of morphological data for zooarchaeological studies of equids in Iberia and throughout Eurasia and Africa. info:eu-repo/semantics/publishedVersion

Strontium isotopes (Sr-87/Sr-86) provide valuable information to help reconstruct past mobility. For the analysis of archaeological tooth enamel to provide a direct assessment of mobility, a comparison to the baseline Sr-87/Sr-86 in a region is required. In this study, a large-scale Sr-87/Sr-86 baseline of Portugal is created based on 151 paired plant and soil leachate samples combined with previously published data (20 additional plant and 33 additional soil leachate sites). Spatial patterns of Sr-87/Sr-86 are evident, following Portugal's geology and terrain, with higher Sr-87/Sr-86 in the granite dominated north and further inland. Influences from sea spray are observed along the coastal regions of the country. The bioavailable strontium range for Portugal is 0.70575-0.73487, and paired plant-soil leachate site measurements show a strong positive relationship. Empirical Bayesian Kriging (EBK) alongside mean Sr-87/Sr-86 per geological unit are used to provide predictive surfaces for bioavailable Sr-87/Sr-86. We find that the addition of archaeological site-specific measurements is required in archaeological mobility studies to ensure local-scale Sr-87/Sr-86 variation is captured, illustrated in this study using the Late Middle Neolithic to Early Bronze Age site of Perdigoes. The bioavailable strontium isoscape for Portugal provides a baseline map for future archaeological and palaeoecological studies in this region and contributes to the global efforts to map strontium isotope variability. ARC Discovery Project DP160100811 Grant agreement number 948913 info:eu-repo/semantics/publishedVersion

Abstract Anemia, a multifactorial condition with an intricate etiology, impacts on worldwide health. In bioarchaeology, cribra orbitalia (CO) and cribra cranii (CC) have been associated with anemia. However, studies point to a complex origin for these lesions allied with pathogenic loads and poor living conditions. Bone elemental composition might help to identify homeostatic ruptures due to anemia and/or cribra. This study hypothesizes that possible homeostatic ruptures due to anemia and CC can cause measurable alterations in bone elemental concentration, particularly in elements such as Ca, P, Fe, Cu and Pb. Twelve elements were measured by non-invasive pXRF, in 45 crania (27 females, 18 males) from the Coimbra Identified Osteological Collections. Individuals were grouped according to cause of death (COD) −19 anemia vs. 26 control - and CO and CC were recorded as present/absent. None of the individuals had CO and 14 expressed CC (4 in the anemic and 10 in the control group). Data from previous studies, and the Ca/P ratio suggest a low diagenetic impact on the sample; however, alteration of bone bioapatite has been identified as the process underlying the first principal component. Individuals with anemia as COD had lower Si content (Cp3), but this element might be under the detection limits. Principal component analysis identified that individuals with CC presented higher levels of Fe and lower of S (Cp2). These elements are in close affinity in the soil, but they are not correlated in this investigation. Hence, their concentrations may be associated with socioeconomic conditions of the Coimbra population in the 19th/20th century. Females presented higher concentration of P and Ca. This might be due to a retention of these elements in young women with demanding physiological roles, yet a diagenetic effect cannot be excluded. Older individuals presented lower concentrations of P, Ca, and Cl and higher of Pb. These differences may be associated with the normal aging process and with the fact that fragile skeletons are more prone to post-mortem alterations. Portable XRF proved to be a useful tool for the study of documented individuals and bone elemental composition may contribute to the etiological discussion of anemia and CC, as well as the taphonomic process.

Glass mosaic decorations were used throughout the medieval Mediterranean as a powerful medium to convey religious and political agendas, yet we know next to nothing about the source of the materials and the transmission of the necessary technical know-how. Mosaics are generally considered a Byzantine art form, not least due to their prominence in Byzantine church architecture and because medieval Islamic textual sources assert that the glass tesserae of some of the most important early mosques were of Byzantine origin. This article provides solid analytical evidence that glass used in the tenth-century mosaics of the Great Umayyad Mosque of Córdoba (Spain) came from Byzantium. Most of the tesserae have high boron contents, for which the only compositional match are Byzantine glasses made with raw materials from Asia Minor. In addition, some of the glass has a chemical fingerprint that suggests that it was prepared by mixing local raw materials with imported high boron glass, indicative of local mosaic glassmaking. Our study thus illustrates the value of analytical studies in re-assessing long-held assumptions about the making of mosaics as well as the movement of materials and people across cultural barriers. The presence of Byzantine materials and craftsmen in Córdoba demonstrates that Muslims and Christians were interacting the length of the Mediterranean, corroborating the close diplomatic ties between the Caliphate of Córdoba and the Byzantine Empire during the tenth century. Our findings further underscore the importance of glass in trade and diplomatic exchange, reflecting its cultural and economic value in the medieval world. This work has received funding from the Cabildo of Cordoba Cathedral, Spain; Instituto Andaluz del Patrimonio Histórico, the European Research Council under the European Union's Horizon 2020 research and innovation programme (grant agreement No. 647315 to NS), the Fundación General CSIC (ComFuturo Programme), the Portuguese Foundation for Science and Technology (FCT- MCTES) through the Research Unit VICARTE (UIDB/00729/2020) and C2TN (UIDB/04349/2020), the agreements IAPH & UPO, the Projects BIA2015-64878-R (Art-Risk, RETOS project of Ministerio de Economía y Competitividad and Fondo Europeo de Desarrollo Regional) and PID2019-107257RB-I00 (FENIX. RETOS project of Ministerio de Ciencia e Innovación), and the research team TEP-199 from Junta de Andalucía. M.A.G.M. is grateful to CEI PATRIMONIO for her fellowship and to the ENEA (FRASCATI) for her stay as visiting researcher. The authors wish to acknowledge professional support of the Interdisciplinary Thematic Platform from CSIC Open Heritage: Research and Society (PTI-PAIS).

Unlike other Upper Paleolithic industries, Gravettian assemblages from the Swabian Jura are documented solely in the Ach Valley (35-30 Kcal BP). On the other hand, traces of contemporaneous occupations in the nearby Lone Valley are sparse. It is debated whether this gap is due to a phase of human depopulation, or taphonomic issues related with landscape changes. In this paper we present ERT, EC-logging and GPR data showing that in both Ach and Lone valleys sediments and archaeological materials eroded from caves and deposited above river incisions after 37-32 Kcal BP. We argued that the rate of cave erosion was higher after phases of downcutting, when hillside erosion was more intensive. To investigate on the causes responsible for the dearth of Gravettian materials in the Lone Valley we test two alternative hypotheses: i) Gravettian humans occupied less intensively this part of the Swabian Jura. ii) Erosion of cave deposits did not occur at the same time in the two valleys. We conclude that the second hypothesis is most likely. Ages from the Lone Valley show increasing multimillennial gaps between 36 and 18 Kcal BP, while a similar gap is present in the Ach Valley between 28 and 16 Kcal BP. Based on geoarchaeological data from previous studies and presented in this paper, we interpreted these gaps in radiocarbon data as indicating of cave erosion. Furthermore, we argued that the time difference across the two valleys show that the erosion of cave deposits began and terminated earlier in the Lone Valley, resulting in a more intensive removal of Gravettian-aged deposits. The hypothesis that cave erosion was triggered by regional landscape changes seems to be supported by geochronological data from the Danube Valley, which show that terrace formation at the end of the Pleistocene moved westwards throughout southern Germany with a time lag of few millennia. info:eu-repo/semantics/publishedVersion PTDC/HAR-ARQ/27833/2017

Plant resins, tars and organic fossil substances provide valuable insights into the ecological, environmental and cultural contexts of ancient societies. Their study offers evidence of past know-how, production systems, socio-economic networks and mobility. In this paper, we present new data from 16 sites located in the North-West Mediterranean that provide new insights into the exploitation of these substances for their adhesive and hydrophobic properties throughout the Neolithic (6000-2500 cal BCE). The substances investigated are discussed in the light of their molecular composition, their uses and manufacturing processes. Spatial analyses were also performed to elucidate raw material procurement strategies. This study considerably increases the body of data available from the Mediterranean and tells a diachronic story of adhesive production and use throughout the Neolithic, highlighting the variability and complexity of production systems and supply networks at different spatial scales. While most adhesive and hydrophobic substances were probably collected locally, birch bark tar was very likely transported across long distances to reach Mediterranean coastal sites. Birch bark tar exploitation intensified in South-Eastern France during the Middle Neolithic, while the Late Neolithic is characterised by a diversification of the substances employed and their range of uses: bitumen, birch bark tar (pure or mixed with Pinaceae resin, beeswax and possibly fat/oil) were important materials that were used for a variety of purposes. Pure Pinaceae exudates were exclusively employed for waterproofing pottery. We also highlight the standardisation of birch bark tar production for adhesive manufacture observed in Provence during the first part of the 4th millennium cal. BCE. The authors thank the French National Research Agency (ANR) for the funding of the project Exsudarch (2010-2014, M. Regert dir.) which allowed extensive diachronic interdisciplinary investigations on plant exudates and tars as well as researching the biogeography of plant raw materials. We are also grateful to the Academy 5 of the IDEXJEDI from UCA (Université Côte d’Azur), to the MSHS sud-est, to the CNRS-INEE and to the CEPAM for funding the research project ARCHEOPLANTES (2018-2020, M. Regert dir.). The results presented here were obtained during the PhD of Maxime Rageot, funded by the PACA Region, the CNRS and the Université Côte d’Azur; may they find here the expression of our sincere thanks. We are grateful to Nolan Ferar for proofreading the article. Finally, we would like to thank the two reviewers for their constructive suggestions which helped to improve the quality of this article. Peer reviewed

Abstract The use of iron pigments is well documented in the archaeological horizons of the different parts of the world since the Middle Pleistocene. The mineralogical and chemical composition of the pigments allowed defining, in most cases, their inorganic origin, which were then used after a limited transformation and manipulation. The use of a biogenic ochraceous pigment and its manipulation has recently been described in a late Holocene archaeological horizon of the American continent. Here we describe the earliest case of archaeological use of ferrous pigment produced by iron-oxidising bacteria (FeOB), the first identified in a European Epigravettian (late Upper Palaeolithic) layer, at the San Teodoro site in Sicily, Italy. Samples of the ochraceous archaeological deposit, overlying a large burial site, were analysed according to current methods of physical analysis and SEM highlighting a matrix of bacterial structures and a chemical composition coherent with biogenic productions. The physical-chemical analysis of the archaeological material from the Palaeolithic site, and of the modern bacteriogenic iron sediments from two close springs gave consistent results even after heat treatment. In absence of Terra Rossa or other easily available inorganic ferrous materials in the hinterland of their site, the hunter-gatherers identified several possible water sources rich of pigment used for covering a multiple burial. The implications of these results influence interpretations of the ecology of the late-glacial and Epigravettian sites in Europe, especially in relation to problems such as the increasing complexity of behaviours, the need to establish rituals and the search for materials.