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Abstract. Lake Petén Itzá (Guatemala) possesses one of the longest lacustrine sediment records in the northern Neotropics, which enabled study of paleoclimate variability in the region during the last ∼400 000 years. We used geochemical (Ti, Ca/(Ti+Fe) and Mn/Fe) and mineralogical (carbonates, gypsum, quartz, clay) data from sediment core PI-2 to infer past changes in runoff, lake evaporation, organic matter sources and redox conditions in the water column, caused by hydrological changes in the northern Neotropics during Marine Isotope Stages (MISs) 3–2. From 59 to 39 cal ka BP climate conditions were relatively wet, and the lake was marked by higher primary productivity and anoxic bottom waters. This wet environment was interrupted for two periods of possible low water level at 52 and 46 cal ka BP, when our data suggest higher evaporation, high terrestrial organic matter input and persistent oxic conditions. Between 39 and 23 cal ka BP, evaporation and input of terrestrial organic matter increased considerably, lake level declined, and lake bottom waters generally became oxic. These conditions reversed during the Last Glacial Maximum (23.5–18.0 cal ka BP), when runoff and lake productivity increased, and rising lake level caused bottom waters to again become anoxic. Comparison of our hydrologic proxy data with sea surface temperature anomalies between the eastern Pacific and the Caribbean suggests that changes in the intensity of the Caribbean Low-Level Jet (CLLJ) may have influenced long-term changes in runoff during MISs 3–2. Higher intensity of the CLLJ during the onset of MIS 3 and the LGM might have led to greater runoff into the lake, whereas the MIS 3–2 transition experienced a weaker CLLJ and consequently less runoff. A refined, high-resolution age–depth model for the PI-2 sediment core enabled us to identify millennial-scale Greenland interstadials (GIs) 14–2, Greenland stadials (GSs) 14–2 and Heinrich stadials (HSs) 5–1. In general, HSs and GSs were characterized by drier conditions. In contrast to GSs and HSs, GIs were characterized by greater runoff and overall wetter conditions, with the most pronounced GI peaks between 40 and 30 cal ka BP. Whereas GSs 9, 8, 7 and 6 began with abrupt increases in evaporation and ended with gradual increases in humidity, GSs 11 and 10 showed reversed patterns. The Lake Petén Itzá paleohydrology record, along with other regional paleoclimate records, led us to conclude that shifts in the position of the Intertropical Convergence Zone (ITCZ) altered moisture delivery to the lake on millennial timescales. During GSs and HSs, high evaporation from Petén Itzá (dry climate conditions) was associated with a more southerly position of the ITCZ, whereas wetter GIs prevailed during a more northerly ITCZ position. Although abrupt millennial-scale shifts in ITCZ and hydroclimate between GSs/HSs and GIs can be linked to instabilities in the Atlantic Meridional Overturning Circulation (AMOC), longer-term changes were additionally influenced by changes in atmospheric convection linked to modulations of the CLLJ in response to ΔSST between the equatorial Pacific and tropical Atlantic.

AbstractCombined Hf-O isotopic analyses of zircons from tuffs and lavas within the Sierra Madre Occidental (SMO) silicic large igneous province are probes of petrogenetic processes in the lower and upper crust. Existing petrogenetic and tectonomagmatic models diverge, having either emphasized significant crustal reworking of hydrated continental lithosphere in an arc above the retreating Farallon slab or significant input of juvenile mantle melts through a slab window into an actively stretching continental lithosphere. New isotopic data are remarkably uniform within and between erupted units across the spatial and temporal extent of the SMO, consistent with homogeneous melt production and evolution. Isotopic values are consistent with enriched mantle magmas (80%) that assimilated Proterozoic paragneisses (~20%) from the lower crust. δ18Ozircon values are consistent with fractionation of mafic magma and not with assimilation of hydrothermally altered upper crust, suggesting that the silicic magmas evolved at depth. Isotopic data agree with previous interpretations where voluminous juvenile melts entered the lithosphere during the transition from a continental arc experiencing slab rollback (Late Eocene) to the arrival of a subducting slab window (Oligocene and Early Miocene) and failure of the upper plate leading to the opening of the Gulf of California (Late Miocene). An anomalously large heat flux and extension of the upper plate allow for the sustained fractionation of the voluminous SMO magmas and assimilation of the lower crust.

Abstract We reject the notion of a Jurassic continental arc in eastern Mexico, termed the “Nazas arc,” on geologic grounds. Instead, we propose that the Jurassic continental arc of the SW Cordilleran U.S. and northern Sonora, Mexico, passed southward into the oceanic realm and is represented by Jurassic arc volcanic and plutonic rocks that fringed the Mexican paleo-Pacific margin, which are currently found in the western Peninsular Ranges of southern California, USA, and Baja California, the Vizcaino Peninsula of Baja California, and western mainland Mexico. To show this, we present a summary of the geologic features of a continental arc, using the geology of the southern end of the Jurassic continental arc, in southern Arizona and northern Sonora. These features include multi-kilometer–thick sections of volcanic rock; large volcanic centers, including silicic calderas; major eruptive units that can be correlated for distances of 100 km or more; abundant, large plutonic suites; and continuity of these features for distances of hundreds of kilometers along the length of the continental arc. Then we show that the “Nazas arc” consists of scattered, small continental rift basins with thin (meters to tens of meters thick) volcanic sections at the base of clastic sections that are hundreds of meters thick. Plutonic rocks are entirely absent from the “Nazas arc,” despite the fact that post-Jurassic tectonic events should have exposed them if they existed. This paper also presents a tabulation of all published U-Pb zircon dates in the Jurassic continental arc of southern Arizona, USA, and northern Sonora (Table 1A), and in the “Nazas arc” of eastern Mexico (Table 1B), with ages, methods, the rock type dated, and notes on geologic relations. We use this to detail the abundance of thick, laterally extensive volcanic sections and large plutonic suites in a continental arc (the Jurassic arc of southern Arizona–northern Sonora), which contrasts sharply with the “Nazas arc.” The term “Nazas arc” has been in widespread usage for volcanic rocks in eastern Mexico for decades in many dozens of papers, and it is portrayed as a 2000-km-long, 250-km-wide belt that extends from Sonora through eastern Mexico to Chiapas. It has been misunderstood to form a subduction-related silicic large igneous province (SLIP), and it has been proposed that the Gulf of Mexico formed as a backarc basin behind the “Nazas arc.” The “Nazas arc” model also requires an east-dipping subduction zone under Mexico, and a separate west-dipping subduction zone under the oceanic arc rocks of western Mexico, which those models portray as an exotic arc, despite the presence of abundant detrital zircon from the Mexican margin. We urge workers to abandon the term “Nazas arc” and replace it with “Nazas rift province,” which represents continental rift basins formed during the breakup of Pangea.

Abstract Through the lens of bulk-rock and matrix glass geochemistry, we investigated the magmatic evolution and pre-eruptive architecture of the siliceous magma complex beneath the Cerro Blanco volcanic complex, a Crater Lake–type caldera complex in the southern Puna Plateau of the Central Andes of Argentina. The Cerro Blanco volcanic complex has been the site of two caldera-forming eruptions with volcanic explosivity index (VEI) 6+ that emplaced the ca. 54 ka Campo Piedra Pomez ignimbrite and the ca. 4.2 ka Cerro Blanco ignimbrite. As such, it is the most productive recent explosive volcano in the Central Andes. The most recent eruptions (younger than 4.2 ka) are dominantly postcaldera effusions of crystal-rich domes and associated small explosive pulses. Previous work has demonstrated that andesitic recharge of and mixing with rhyolitic magma occurred at the base of the magma complex, at ~10 km depth. New isotopic data (Sr, Nd, Pb, and O) confirm that the Cerro Blanco volcanic complex rhyolite suite is part of a regional southern Puna, arc-related ignimbrite group. The suite defines a tight group of consanguineous siliceous magmas that serves as a model for the evolution of arc-related, caldera-forming silicic magma systems in the region and elsewhere. These data indicate that the rhyolites originated through limited assimilation of and mixing with upper-crustal lithologies by regional basaltic andesite parent materials, followed by extensive fractional crystallization. Least squares models of major elements in tandem with Rayleigh fractionation models for trace elements reveal that the internal variations among the rhyolites through time can be derived by extensive fractionation of a quartz–two feldspar (granitic minimum) assemblage with limited assimilation. The rare earth element character of local volumes of melt in some samples of the Campo Piedra Pomez ignimbrite basal fallout requires significant fractionation of amphibole. The distinctive major- and trace-element characteristics of bulk rock and matrix of the Campo Piedra Pomez and Cerro Blanco tephras provide useful geochemical fingerprints to facilitate regional tephrochronology. Available data indicate that rhyolites from other neighborhood centers, such as Cueros de Purulla, share bulk chemical characteristics with the Campo Piedra Pomez ignimbrite rhyolites, but they appear to be isotopically distinct. Pre-eruptive storage and final equilibration of the rhyolitic melts were estimated from matrix glass compositions projected onto the haplogranitic system (quartz-albite-orthoclase-H2O) and using rhyolite-MELTS models. These revealed equilibration pressures between 360 and 60 MPa (~10–2 km depth) with lowest pressures in the Holocene eruptions. Model temperatures for the suite ranged from 695 to 790 °C. Integrated together, our results reveal that the Cerro Blanco volcanic complex is a steady-state (low-magmatic-flux), arc-related complex, standing in contrast to the flare-up (high-magmatic-flux) supervolcanoes that dominate the Neogene volcanic stratigraphy. The silicic magmas of the Cerro Blanco volcanic complex were derived more directly from mafic and intermediate precursors through extensive fractional crystallization, albeit with some mixing and assimilation of local basement. Geochemical models and pressure-temperature estimates indicate that significant volumes of remnant cumulates of felsic and intermediate composition should dominate the polybaric magma complex beneath the Cerro Blanco volcanic complex, which gradually shallowed through time. Evolution to the most silicic compositions and final equilibration of some of the postcaldera domes occurred during ascent and decompression at depths less than 2 km. Our work connotes an incrementally accumulated (over at least 54 k.y.), upper-crustal pluton beneath the Cerro Blanco volcanic complex between 2 and 10 km depth. The composition of this pluton is predicted to be dominantly granitic, with deeper parts being granodioritic to tonalitic. The progressive solidification and eventual contraction of the magma complex may account for the decades of deflation that has characterized Cerro Blanco. The presently active geothermal anomaly and hydrothermal springs indicate the Cerro Blanco volcanic complex remains potentially active.

Abstract. Volcanic signatures archived in polar ice sheets provide important opportunities to date and correlate ice-core records as well as to investigate the environmental impacts of eruptions. Only the geochemical characterization of volcanic ash (tephra) embedded in the ice strata can confirm the source of the eruption, however, and is a requisite if historical eruption ages are to be used as valid chronological checks on annual ice layer counting. Here we report the investigation of ash particles in a Greenland ice core that are associated with a volcanic sulfuric acid layer previously attributed to the 79 CE eruption of Vesuvius. Major and trace element composition of the particles indicates that the tephra does not derive from Vesuvius but most likely originates from an unidentified eruption in the Aleutian arc. Using ash dispersal modelling, we find that only an eruption large enough to include stratospheric injection is likely to account for the sizeable (24–85 μm) ash particles observed in the Greenland ice at this time. Despite its likely explosivity, this event does not appear to have triggered significant climate perturbations, unlike some other large extra-tropical eruptions. In light of a recent re-evaluation of the Greenland ice-core chronologies, our findings further challenge the previous dating of this volcanic event to 79 CE. We highlight the need for the revised Common Era ice-core chronology to be formally accepted by the wider ice-core and climate modelling communities in order to ensure robust age linkages to precisely dated historical and paleoclimate proxy records.

AbstractA particular type of miniature ceramic vessel locally known as “veneneras” is occasionally found during archaeological excavations in the Maya Area. To date, only one study of a collection of such containers successfully identified organic residues through coupled chromatography–mass spectrometry methods. That study identified traces of nicotine likely associated with tobacco. Here we present a more complete picture by analyzing a suite of possible complementary ingredients in tobacco mixtures across a collection of 14 miniature vessels. The collection includes four different vessel forms and allows for the comparison of specimens which had previously formed part of museum exhibitions with recently excavated, untreated containers. Archaeological samples were compared with fresh as well as cured reference materials from two different species of tobacco (Nicotiana tabacum and N. rustica). In addition, we sampled six more plants which are linked to mind-altering practices through Mesoamerican ethnohistoric or ethnographic records. Analyses were conducted using UPLC-MS metabolomics-based analytical techniques, which significantly expand the possible detection of chemical compounds compared to previous biomarker-focused studies. Results include the detection of more than 9000 residual chemical features. We trace, for the first time, the presence of Mexican marigold (Tagetes lucida) in presumptive polydrug mixtures.

For the first time in the history of ground-based $\gamma$-ray astronomy, the on-axis performance of the dual mirror, aspheric, aplanatic Schwarzschild-Couder optical system has been demonstrated in a $9.7$-m aperture imaging atmospheric Cherenkov telescope. The novel design of the prototype Schwarzschild-Couder Telescope (pSCT) is motivated by the need of the next-generation Cherenkov Telescope Array (CTA) observatory to have the ability to perform wide ($\geq 8^{\circ}$) field-of-view observations simultaneously with superior imaging of atmospheric cascades (resolution of $0.067^{\circ}$ per pixel or better). The pSCT design, if implemented in the CTA installation, has the potential to improve significantly both the $\gamma$-ray angular resolution and the off-axis sensitivity of the observatory, reaching nearly the theoretical limit of the technique and thereby making a major impact on the CTA observatory sky survey programs, follow-up observations of multi-messenger transients with poorly known initial localization, as well as on the spatially resolved spectroscopic studies of extended $\gamma$-ray sources. This contribution reports on the initial alignment procedures and point-spread-function results for the challenging segmented aspheric primary and secondary mirrors of the pSCT. Comment: 19 pages, 11 figures, proceedings for SPIE Optical Engineering + Applications, 2020, Online Only