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Abstract After decades of operation in nuclear power plants, Once-Through Steam Generators (OTSGs) were recently proposed for nuclear fusion applications. In particular, they are supposed to be installed in the primary cooling systems of the European Union Demonstration fusion power plant (EU-DEMO). One of the key reactor components is the Breeding blanket (BB). Among the BB concepts that are currently under study, Water-Cooled Lithium-Lead (WCLL) option was considered for this work. The WCLL blanket is divided in two main subsystems, the breeder zone (BZ) and the first wall (FW), each one provided with an independent cooling circuit, named Primary Heat Transfer System (PHTS). Thermal power removed from BB by BZ and FW PHTS is driven to the Power Conversion System (PCS) to be converted into electricity. The thermal coupling is ensured by two OTSGs per system. At the Department of Astronautical, Electrical and Energy Engineering (DIAEE) of Sapienza University of Rome, a simulation activity was carried out to understand the component thermal-hydraulic behavior during DEMO normal operations. For calculation purposes, a full model of the steam generator was prepared by using a modified version of RELAP5/MOD3.3 system code. The computational activity performed allows to preliminary characterize the OTSG thermal-hydraulic performances during both pulse and dwell phases.

Abstract In fusion reactor blanket design, liquid metals are attractive working fluids since it is possible to combine in a single fluid the functions of coolant, tritium carrier and breeder. These electrically conductive fluids flow in the presence of a strong magnetic field, inducing the appearance of Lorentz forces and magnetohydrodynamic MHD effects. Increased pressure loss, particularly in complex geometry elements, is a critical point for blanket design. The MHD flow through an orifice plate made by electroconductive walls (c = 0.01 ÷ 0.1) has been analysed in this paper using ANSYS CFX in the range Re = 108, and Ha = 0 ÷ 300. A wide recirculation region is detected after the flow exits the orifice, with potentially harmful consequences for efficient tritium removal. Large pressure loss occurs in the orifice due to conductive wall and non-negligible axial length. The 3D pressure drop term is characterized through a local resistance coefficient (k) that is found to be k ≈ 0.205 for well conducting walls (c = 0.1) and k ≈ 0.063 for poorly conducting ones (c = 0.01).

The tempo and mode of Homo sapiens dispersal in Eurasia and the demise of Neanderthals has sparked debate about the dynamics of Neanderthal extinction and its relationship to the arrival of H. sapiens. In Italy, the so-called ‘Transition’ from Neanderthals to H. sapiens is related to the Uluzzian technocomplex, i.e. the first archaeological evidence for modern human dispersal on the European continent. This paper illustrates the new chronology and stratigraphy of Uluzzo C, a rock shelter and Uluzzian key site located in the Uluzzo Bay in southern Italy, where excavations are ongoing, refining the cultural sequence known from previous excavations. Microstratigraphic investigation suggests that most of the deposit formed after dismantling of the vault of the rock shelter and due to wind input of loess deflated by the continental shelf. The occasional reactivation of the hydrology of the local karst system under more humid conditions further contributed to the formation of specific layers accumulating former Terra Rossa-type soil fragments. Superposed on sedimentary processes, strong bioturbation and the mobilization and recrystallization of calcite have been detected. Optically stimulated luminescence (OSL) ages from Uluzzo C Rock Shelter are congruent with previously published radiocarbon ages obtained on shell beads and tephrachronology from adjacent sites preserving the Uluzzian technocomplex such as Grotta del Cavallo, confirming the onset for the Uluzzian in the area to ca. 39.2–42.0 ka. The OSL chronology from Uluzzo C also provides a terminus post quem for the end of the Mousterian in the region, constraining the disappearance of the Neanderthals in that part of Italy to ≥46 ± 4 ka.

AbstractThis work explores the relationship between multinational R&D and innovation productivity among top corporate knowledge and R&D producers by adopting a twofold concept of internationalisation: (1) the firm’s degree of R&D internationalisation, and (2) the firm’s geographic diversification. We model the patent production process with an appropriate and robust conditional Data Envelopment Analysis (DEA) estimator, using a unique database of firms that matches financial indicators and patent information. Our results reinforce the fundamental role of internationalisation in the knowledge production process when the internationalisation process is properly and strategically managed. We interpret our empirical evidence through the theoretical lens of the learning theory of internationalisation, and we postulate that a high R&D intensity is a key driver to overcoming the challenges of internationalisation.

The Middle to Upper Palaeolithic transition, between 50 000 and 40 000 years ago, is a period of important ecological and cultural changes. In this framework, the Rock Shelter of Uluzzo C (Apulia, southern Italy) represents an important site due to Late Mousterian and Uluzzian evidence preserved in its stratigraphic sequence. Here, we present the results of a multidisciplinary analysis performed on the materials collected between 2016 and 2018 from the Uluzzian stratigraphic units (SUs) 3, 15 and 17. The analysis involved lithic technology, use-wear, zooarchaeology, ancient DNA of sediments and palaeoproteomics, completed by quartz single-grain optically stimulated luminescence dating of the cave sediments. The lithic assemblage is characterized by a volumetric production and a debitage with no or little management of the convexities (by using the bipolar technique), with the objective to produce bladelets and flakelets. The zooarchaeological study found evidence of butchery activity and of the possible exploitation of marine resources, while drawing a picture of a patchy landscape, composed of open forests and dry open environments surrounding the shelter. Ancient mitochondrial DNA from two mammalian taxa were recovered from the sediments. Preliminary zooarchaeology by mass spectrometry results are consistent with ancient DNA and zooarchaeological taxonomic information, while further palaeoproteomics investigations are ongoing. Our new data from the re-discovery of the Uluzzo C Rock Shelter represent an important contribution to better understand the meaning of the Uluzzian in the context of the Middle/Upper Palaeolithic transition in south-eastern Italy.

Two metallurgical traditions coexisted in the Chalcolithic Southern Levant: the lost wax casting of polymetallic alloys and the pure copper technology. Details of their operational sequences are still unknown. To date, no production sites of lost wax casting technology have been found. Only the main steps of the pure copper technology can be reconstructed from the archaeological record. Therefore, an archaeological experiment was carried out to shed new light on both technologies. Concerning the pure copper technology, the experiment focussed on the draught technique and high-temperature behaviour of the crucible and furnace clays. Based on archaeological evidence, a furnace and crucibles were reconstructed with local clays used by ancient metallurgists. Instead of the commonly hypothesised blowpipes, bellows were used to produce the draught. The furnace was successfully operated with bellows and reached temperatures high enough to melt copper. Furthermore, the clays’ behaviour varied considerably due to high heat exposure, but they are suitable if used appropriately. Our experiment establishes this draught technique as a viable alternative to the commonly assumed blowpipes as well as the suitability of local clays.

Abstract In this paper we investigated the calculation of the anodic limit of two anions of ionic liquids, largely used as electrolyte of lithium batteries. Starting from a model based on calculations performed on single ions at the MP2 level of theory, we showed that the matching between calculation and experiments decreases while using more expanded basis set with respect to 6-31G**, possibly because of the destabilization of the neutral species when larger basis sets are considered. Additionally, in order to decrease the computational time, the performances for the calculation of the anodic limit obtained by means of a series of DFT functionals with increasing level of complexity (from the Generalized Gradient Approximation to the Range Separated Hybrid meta-Generalized Gradient Approximation) were compared. Overall, the best performing functionals are BMK, ωB97M-V and MN12-SX, while acceptable results can be obtained by M06-2X, M11, M08-HX and M11-L. Some less computationally expensive functionals, like CAM-B3LYP and ωB97X-D, also provide reasonable values of the anodic limit.

In the American West, wildfires and earthquakes are increasingly threatening the archaeological, historical, and tribal resources that define the collective identity and connection with the past for millions of Americans. The loss of said resources diminishes societal understanding of the role cultural heritage plays in shaping our present and future. This paper examines the viability of employing stationary and SLAM-based terrestrial laser scanning, close-range photogrammetry, automated surface change detection, GIS, and WebGL visualization techniques to enhance the preservation of cultural resources in California. Our datafication approach combines multi-temporal remote sensing monitoring of historic features with legacy data and collaborative visualization to document and evaluate how environmental threats affect built heritage. We tested our methodology in response to recent environmental threats from wildfire and earthquakes at Bodie, an iconic Gold Rush-era boom town located on the California and Nevada border. Our multi-scale results show that the proposed approach effectively integrates highly accurate 3D snapshots of Bodie’s historic buildings before/after disturbance, or post-restoration, with surface change detection and online collaborative visualization of 3D geospatial data to monitor and preserve important cultural resources at the site. This study concludes that the proposed workflow enhances the monitoring of at-risk California’s cultural heritage and makes a call to action to employ remote sensing as a pathway to advanced planning.

The high artistic and cultural relevance of particular objects, in this case from the Nuragic civilization, have stimulated the growth of a forgery industry, replicating small bronze boats (navicelle), statues (bronzetti), and other objects. It is often the case where the forgeries are of such quality that it becomes difficult to distinguish them from authentic artifacts without a proper chemical analysis. In this research, a Monte Carlo simulation algorithm for X-ray interactions with matter is used to obtain the chemical composition from the bulk of each object from a set of five. The method employed has the advantage of being completely nondestructive and relatively fast. The objects’ chemical composition and morphology were compared with the data available from authentic artifacts so their authenticity could be inferred. Four of the five objects are likely to be authentic, where two of them could be associated with a Sardinian origin.